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Raman Spectroscopy of Conformational Rearrangements at Low Temperatures: Folding
AU $223.30
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eBay item number:135301573162
Item specifics
- Condition
- ISBN-13
- 9783319359762
- Book Title
- Raman Spectroscopy of Conformational Rearrangements at Low Temper
- ISBN
- 9783319359762
- Publication Year
- 2016
- Type
- Textbook
- Format
- Paperback
- Language
- English
- Publication Name
- Raman Spectroscopy of Conformational Rearrangements at Low Temperatures: Folding and Stretching of Alkanes in Supersonic Jets
- Item Height
- 235 mm
- Publisher
- Springer International Publishing Ag
- Subject
- Chemistry, Physics
- Item Weight
- 3051 g
- Item Width
- 155 mm
- Number of Pages
- 183 Pages
About this product
Product Information
This thesis identifies the turning point in chain length, after which alkanes self-solvate into a folded structure instead of an extended stretched conformation. After this turning point, London dispersion forces rearrange isolated n-alkanes into a particular hairpin-structure, while for shorter chain lengths, a simple stretched conformation is energetically preferred. This thesis can locate the experimental turning point for the first time in an interaction-free manner from measurements of unbranched alkanes at low temperatures in supersonic jet expansions. It contains a detailed analysis of the vibrational Raman spectra of the chain molecules, which is supported by comprehensive quantum chemical simulations. In this way, the detailed balance between inter-chain attraction and conformational flexibility can be quantified. The investigations are complemented by measurements of perfluoroalkanes and similarities and differences between the compounds are discussed. Furthermore, Nils Luttschwager determines the stiffnesses (elastic moduli) of two of the most common industrial polymers: polyethylene and polytetrafluorethylene. He uses in this thesis a sophisticated extrapolation to calculate this value from quantities of their building blocks, showing that the single polymer molecules can be as stiff as a rod of steel.
Product Identifiers
Publisher
Springer International Publishing Ag
ISBN-13
9783319359762
eBay Product ID (ePID)
228724522
Product Key Features
Number of Pages
183 Pages
Language
English
Publication Name
Raman Spectroscopy of Conformational Rearrangements at Low Temperatures: Folding and Stretching of Alkanes in Supersonic Jets
Publication Year
2016
Subject
Chemistry, Physics
Type
Textbook
Format
Paperback
Dimensions
Item Height
235 mm
Item Weight
3051 g
Item Width
155 mm
Additional Product Features
Country/Region of Manufacture
Switzerland
Series Title
Springer Theses
Item description from the seller
Seller business information
VAT number: AU 82107909133, GB 293967539
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Seller feedback (1,456,832)
- c***c (446)- Feedback left by buyer.Past monthVerified purchaseA reliable and professional seller offering a wide range of items. Not always the cheapest option but certainly a store upon which you can depend. My goods were dispatched promptly, packaged appropriately and, upon receipt, found to be exactly as described. Communication throughout the process was good and I'd have no hesitation in purchasing from here in the future.
- e***s (300)- Feedback left by buyer.Past monthVerified purchaseGreat seller! Quality product, arrived as described, mint condition. Packaged well, a great value for this product, cosmetic appearance matched the listing, super fast shipping and flawless communication. A++
- k***k (518)- Feedback left by buyer.Past monthVerified purchase🪷 Great communication. .🌻Well packaged and fast postage.✨️ book is as described and great value for money.🌷 highly recommend seller. Will purchase from again.🦋 Thank you!🙂